The wavelength-regulated stereodivergent synthesis of (Z)- and (E)-1,4-enediones from phosphonium ylides

文献情報

出版日 2021-09-06

DOI 10.1039/D1QO01085A

インパクトファクター 5.281

著者

Mei Wang, Yong-Qin He, Yao Zhu, Zhi-Bin Song, Xiao-Yu Wang, Hai-Yang Huang, Ban-Peng Cao, Wan-Fa Tian, Qiang Xiao

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要旨

The wavelength-regulated, methylene blue organic dye catalyzed stereodivergent synthesis of (Z)- and (E)-1,4-enediones from stabilized phosphorous ylides is reported. Broad ranges of substrates and functional groups are tolerated. Mechanistic studies suggested singlet-oxygen-promoted (E)-alkene formation via a possible phospha-1,2-dioxetane intermediate, followed by a blue-LED triggered (E) → (Z) isomerization reaction.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

The wavelength-regulated stereodivergent synthesis of (Z)- and (E)-1,4-enediones from phosphonium ylides

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