Cu-Catalyzed highly selective silylation and borylation of alkenylsulfonium salts

文献情報

出版日 2021-08-06

DOI 10.1039/D1QO00922B

インパクトファクター 5.281

著者

Rong Xie, Jie Zhu, Yinhua Huang

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要旨

A Cu-catalyzed highly selective silylation and borylation of alkenylsulfonium salts under mild conditions is reported. The reaction provides easy access to various alkenylsilanes and alkenylboranes by forming a C–Si/B bond at the alkenyl moiety of alkenylsulfonium salts with high stereoselectivity, a broad substrate scope and tolerance to various functional groups.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Cu-Catalyzed highly selective silylation and borylation of alkenylsulfonium salts

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