Visible-light-induced iodine-anion-catalyzed decarboxylative/deaminative C–H alkylation of enamides

文献情報

出版日 2021-06-07

DOI 10.1039/D1QO00660F

インパクトファクター 5.281

著者

Jia-Xin Wang, Ya-Ting Wang, Hao Zhang, Ming-Chen Fu

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要旨

A visible-light-induced iodine-anion-catalyzed C–H stereoselective alkylation of enamides has been developed. Redox-active esters and Katritzky salts of amino acids were found to be amenable for decarboxylative/deaminative cross-coupling reactions, delivering various functionalized enamides with excellent functional group tolerance. The reaction proceeded via photoactivation of the transiently assembled chromophores, avoiding the use of exogenous precious photoredox catalysts.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Visible-light-induced iodine-anion-catalyzed decarboxylative/deaminative C–H alkylation of enamides

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