Photo-induced weak base-catalyzed synthesis of α-haloboronates from vinylboronates and polyfluoroalkyl halides

文献情報

出版日 2021-02-26

DOI 10.1039/D1QO00169H

インパクトファクター 5.281

著者

Tongchang Fang, Jian Qiu, Kai Yang

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要旨

Organoboron compounds play an important role in various fields due to the diverse transformations of C–B bonds. The introduction of easy-to-transform functional groups into organoboron compounds would greatly increase their synthetic application value. This article reports the first synthesis of sp2-α-haloboronates via an in situ α-sp3-boron radical intermediate, and proved their high synthetic application value through subsequent transformations.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Photo-induced weak base-catalyzed synthesis of α-haloboronates from vinylboronates and polyfluoroalkyl halides

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