Unprecedentedly high active organocatalysts for the copolymerization of carbonyl sulfide and propylene oxide: steric hindrance effect of tertiary amines

文献情報

出版日 2021-08-23

DOI 10.1039/D1PY01013A

インパクトファクター 5.582

著者

Jiraya Kiriratnikom, Xin-Chen Yue, Jia-Liang Yang, Ying Wang, Shuo-Hong Chen, Ke-Ke Zhang, Cheng-Jian Zhang, Munir Ullah Khan

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要旨

The copolymerization of carbonyl sulfide (COS) with epoxides has been developed to be a facile method to synthesize well-defined sulfur-containing polymers. This work describes the steric effect of tertiary amines on the copolymerization of COS with propylene oxide (PO) via a zwitterionic approach, using triethyl borane (TEB) accompanied by various tertiary amines. N,N-Dimethylcyclohexylamine accompanied by TEB (1/1) showed an exceedingly high turnover frequency of up to 69 800 h−1 and a copolymer selectivity of up to >99% for organocatalytic COS/PO copolymerization at 60 °C under solvent-free conditions. The obtained poly(propylene monothiocarbonate)s (PPMTC)s have fully alternating sequences, regioregularity of >99% tail-to-head (T–H) content, and high-number average molecular weights of up to 221.8 kg mol−1 and narrow dispersities (1.1–1.3) within 1 min. We disclosed that tertiary amines (pKa values range from 8.19 to 10.80) with less steric hindrance exhibited higher catalytic activity for COS/PO copolymerization.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

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Unprecedentedly high active organocatalysts for the copolymerization of carbonyl sulfide and propylene oxide: steric hindrance effect of tertiary amines

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