Polyesters with bio-based ferulic acid units: crosslinking paves the way to property consolidation

文献情報

出版日 2021-08-23

DOI 10.1039/D1PY00851J

インパクトファクター 5.582

著者

Doris Pospiech, Andreas Korwitz, Hartmut Komber, Dieter Jehnichen, Kerstin Arnhold, Harald Brünig, Holger Scheibner, Michael T. Müller

原文を見る

要旨

Aromatic–aliphatic polyesters can be prepared as bio-based materials by incorporating monomers from biogenic sources. Here, 2-methyl (E)-3-(4-(2-hydroxyethoxy)-3-methoxyphenyl)acrylate, a derivative of ferulic acid, was synthesised and inserted into the structure of aliphatic and aromatic–aliphatic polyesters as a comonomer. Terpolymers with high relative molar masses Mw from 50 000 to 100 000 g mol−1 can be successfully prepared by transesterification polycondensation in the melt. Incorporation of ferulate units with intact double bonds is proven by NMR spectroscopy. Insertion of low molar amounts of ferulate units reduces the crystallinity of the base polyesters, but enhances the glass transition temperature. It is demonstrated that the materials after melt processing to a suitable shape (fibres, parts, films) can be crosslinked by electron beam irradiation, which enhances the stability of the materials.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Polyesters with bio-based ferulic acid units: crosslinking paves the way to property consolidation

文献情報

おすすめジャーナル

関連文献

Highly efficient bromination of aromatic compounds using 3-methylimidazolium tribromide as reagent/solvent

Fabrication of a stable inorganic–organic hybrid multilayer film with uniform and dense inorganic nanoparticle deposition

Cyclodehydrogenation of di- and tetra(benzimidazol-2-yl)benzenes to give model heteroaromatic discotic systems

Gold and silver nanoparticles functionalized with known numbers of oligonucleotides per particle for DNA detection

A novel catalyst with high activity for polyhydric alcohol oxidation: nanosilver/zeolite film

Direction control in DNA binding of chiral d-lysine-based peptide nucleic acid (PNA) probed by electrospray mass spectrometry

Reactivity of a N-heterocyclic carbene, 1,3-di-(1-adamantyl) imidazol-2-ylidene, with a pseudo-acid: structural characterization of Claisen condensation adduct

From atactic to isotactic CO/p-methylstyrenecopolymer by proper modification of Pd(ii) catalysts bearing achiral α-diimines

Cyclopropyl fatty acids implicate a radical but not a cation as an intermediate in P450BM3-catalysed hydroxylations

Synthesis of monodisperse chromium nanoparticles from the thermolysis of a Fischer carbene complex

こちらもおすすめ

環戊烷-1,3-二甲酸甲酯はどのように合成されますか？

4-メトキシ-1,2,3-スチアゼ-3,5-ジオンとは何ですか？

プロスタグランジンA2について「に適用される法規ガイドラインは何ですか？'

4-アミノ-1-ナフタレン sulfonic 酸についての物理化学的性質は何ですか？

N-GlcNAc-生物素を取り扱う際の実験室安全事項は何ですか？

3-アミノメチルフローラノピペリジン-1-カルボニル酸テルブチルエステルとは何ですか？

6-溴-1-甲基-1H-ベンゾ[d][1,2,3]三氮唑はどのように合成されますか？

4-硫代尿苷はどのように合成されますか？

ブレインナトリユリックペプチド32ラットとは何ですか？

1-(3-氮杂啶)-4-羟基哌啶双盐酸盐の物理化学的性質は何ですか？

掲載誌

Polymer Chemistry

おすすめ化合物

4-Bromo-1-methylpiperidine

5,7,8'-Trihydroxy-2',2'-dimethyl-2'H,4H-3,6'-bichromen-4-one

N,N'-1,2-Ethanediylbis[2-(vinylsulfonyl)acetamide]

Ethyl 3-amino-3-phenylpropanoate

N-[(9H-Fluoren-9-ylmethoxy)carbonyl]-beta-phenyl-L-phenylalanine

おすすめサプライヤー