Triplet–triplet annihilation photon upconversion from diphenylhexatriene and ring-substituted derivatives in solution
文献情報
Toshiko Mizokuro, Kenji Kamada, Yoriko Sonoda
We report that diphenylhexatriene (DPH) and its ring-substituted derivatives act as emitter molecules in triplet–triplet annihilation photon upconversion (TTA-UC). A palladium porphyrin derivative, meso-tetraphenyl-tetrabenzoporphine palladium complex (PdTPBP), which acts as a sensitiser in TTA-UC, and DPH derivatives were dissolved in tetrahydrofuran (THF). The solution showed blue-green to green UC emission under photoexcitation at 640 nm in a nitrogen atmosphere. The UC quantum efficiency (ηUC) values of the DPHs were estimated, with (E,E,E)-1,6-bis[4-(di-2-picolylamino)phenyl]hexa-1,3,5-triene (pico DPH) showing the highest. In addition, the quantum yields of triplet energy transfer (TET) and triplet–triplet annihilation (TTA), which are elementary processes in TTA-UC, were estimated, as well as the triplet lifetimes of each DPH derivative. The results indicate that the TTA process governs the value of ηUC.
おすすめジャーナル

Russian Chemical Reviews

Journal of Physics and Chemistry of Solids

Israel Journal of Chemistry

Journal of Organometallic Chemistry

Helvetica Chimica Acta

Molecular Pharmacology

Journal of Medicinal Chemistry

Organic Preparations and Procedures International

Proceedings of the National Academy of Sciences of the United States of America

Journal of Catalysis
関連文献
Dissociation of ammonia borane and its subsequent nucleation on the Ru(0001) surface revealed by density functional theoretical simulations
Huanhuan Li, Ruiqi Zhao
DOI: 10.1039/D1CP05957B
Quantum simulations of thermally activated delayed fluorescence in an all-organic emitter
Tommaso Francese, Arpan Kundu, Francois Gygi
DOI: 10.1039/D2CP01147F
High electron affinity triggered by lithium coordination: quasi-chalcogen properties of Li2Sn8Be
Duomei Xue, Zeren Chen, Jingyao Liu, Di Wu, Zhiru Li, Ying Li
DOI: 10.1039/D2CP00967F
Photochemistry of 2-thiooxazole: a plausible prebiotic precursor to RNA nucleotides
Lauren Bertram, Matthew W. Powner
DOI: 10.1039/D2CP03167A
Designing SnS/MoS2 van der Waals heterojunction for direct Z-scheme photocatalytic overall water-splitting by DFT investigation
Xiaofang Jia, Jinlong Wang, Yue Lu, Jiaming Sun, Yang Li, Yuyan Wang, Junying Zhang
DOI: 10.1039/D2CP02692A
Revisiting the K-edge X-ray absorption fine structure of Si, Ge–Si alloys, and the isoelectronic series: CuBr, ZnSe, GaAs, and Ge
J. C. Woicik
DOI: 10.1039/D2CP00912A
Theoretical predictions of phase stability for orthorhombic and hexagonal ternary MAB phases
Adam Carlsson, Johanna Rosen, Martin Dahlqvist
DOI: 10.1039/D1CP05750B
sp2-to-sp3 transitions in graphite during cold-compression
Xiaohong Yuan, Yong Cheng, Pei Wang, Fuyang Liu, Songbai Han, Jinlong Zhu, Ming-Sheng Wang, Liping Wang
DOI: 10.1039/D2CP00178K
The protein-stabilizing effects of TMAO in aqueous and non-aqueous conditions
Daron M. Standley, Tomoko Matsuda, Mohammad Reza Housaindokht
DOI: 10.1039/D2CP01279K
In situ activation of green sorbents for CO2 capture upon end group backbiting
Maysoon I. Saleh, Hatem M. Alsyouri, Malyuba A. Abu-Daabes, Ala'a F. Eftaiha, Khaleel I. Assaf, Rania Abu-Zaid, Adnan S. Abu-Surrah, Carsten Troll, Bernhard Rieger
DOI: 10.1039/D2CP00837H
こちらもおすすめ
(S)-四氢呋喃-3-羧酸の物理化学的性質は何ですか?
CAS番号168395-26-4の(S)-四氢呋喃-3-羧酸は、白色の結晶が特徴的な性質を持ちます。分子量は128.08であり、水に溶けやすく、アルコールなど...
塩基性硫黄化合物1,3-ジメチル-1-[5-(三氟甲基)-1,3,4-硫杂环己二酮-2-基]尿素を含む廃棄物はどのように処理すべきですか?
塩基性硫黄化合物1,3-ジメチル-1-[5-(三氟甲基)-1,3,4-硫杂环己二酮-2-基]尿素を含む廃棄物は、専門的な廃棄処理施設で焼却処理を行うべきです。ま...
インドリジン-2-カルボン酸は安全ですか?
インドリジン-2-カルボン酸は一般的に安全ですが、過度に濃い状態では刺激性があります。取り扱いには適切な防護具を使用し、直接触れや吸入を避ける必要があります。
5-甲基-2-(3-ピリジニル)-1,3-テイゾール-4-オールの市場動向や研究トレンドはどうですか?
5-甲基-2-(3-ピリジニル)-1,3-テイゾール-4-オールは、医薬品や農薬、および合成化学の分野において研究が進められています。市場動向としては、化学物質...
4,4',4''-(嘧啶-2,4,6-三基)三苯甲醛はどのように保存すればよいですか?
4,4',4''-(嘧啶-2,4,6-三基)三苯甲醛は、密閉容器に保管し、避けておくことが重要です。室温で保管し、直射日光を避けてください。
(3aR)-1,3,3-トリフェニルテトラヒドロ-3H-ピロロ[1,2-c][1,3,2]-オキザボロロールについて、適用される法規ガイドラインは何ですか?
(3aR)-1,3,3-トリフェニルテトラヒドロ-3H-ピロロ[1,2-c][1,3,2]-オキザボロロールは、GHS(国際危険物識別ルール)の分類が適用されま...
6-(4-氯苯氧基)吡啶-3-胺の代替品はありますか?
6-(4-氯苯氧基)吡啶-3-胺の代替品としては、他の芳香族アミン化合物や類似の除草剤が考えられます。ただし、他の化合物と同様に、代替品の選択には安全性と効果性...
3-フェニル-3,4-ジヒドロ-2H-1,4-ベンゾキサジンを取り扱う際の実験室安全事項は何ですか?
3-フェニル-3,4-ジヒドロ-2H-1,4-ベンゾキサジンを取り扱う際は、防塵マスク、ゴーグル、ゴム手袋を使用し、ドラフトチャンバー内で作業することを推奨しま...
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.




