Self-assembled, optically-active {naphthalene diimide}U{cucurbit[8]uril} ensembles in an aqueous environment
文献情報
Heather F. Higginbotham, Subashani Maniam, Tina Hsia, Lyle Isaacs, Steven J. Langford, Toby D. M. Bell
Naphthalene diimides (NDIs) are shown to arrange spontaneously co-facially with cucurbit[8]uril (CB[8]) in an aqueous environment through purely non-covalent interactions. The resultant 2 : 2 supramolecular complex of NDI and CB[8] is highly fluorescent (>30 times more than the constituent NDIs) due to the formation of NDI–NDI excimers within the supramolecular complex.
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