Macrocyclic and acyclic supramolecular elements for co-precipitation of square-planar gold(iii) tetrahalide complexes

文献情報

出版日 2021-01-28

DOI 10.1039/D0QO01562H

インパクトファクター 5.281

著者

Cassandra C. Shaffer, Bradley D. Smith

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要旨

Macrocyclic hosts have long been used for guest encapsulation, and recently a new application has emerged; employment as supramolecular elements for capture and recovery of gold through host/guest co-precipitation. The guests are square-planar tetrahaloaurate anions, practically important gold complexes with a capacity to engage in non-covalent interactions such as hydrogen bonding and Au–π interactions. The successful macrocyclic hosts for co-precipitation include cyclodextrins, cucurbiturils, and cyclophanes, with recent expansion of the structural scope to include acyclic amides.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Macrocyclic and acyclic supramolecular elements for co-precipitation of square-planar gold(iii) tetrahalide complexes

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