A self-assembled tetrathiafulvalene box

文献情報

出版日 2021-01-08

DOI 10.1039/D0QO01543A

インパクトファクター 5.281

著者

Vincent Croué, Olivier Alévêque, Eric Levillain, Magali Allain, Cécile Mézière, Vincent Carré, Frédéric Aubriet, Zoia Voïtenko, Sébastien Goeb, Marc Sallé

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要旨

A M8L2 metalla-cage constructed through coordination-driven self-assembly from a quinonato bis-ruthenium complex and an electron-rich tetrathiafulvalene (TTF) tetrapyridyl ligand is depicted. In this molecular box, both TTF units are highly bent and are separated by a distance as short as 3.48 Å in the solid state. This system offers a unique opportunity to study the electronic interactions occurring between two TTF units facing each other in a conformationally rigid environment.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

A self-assembled tetrathiafulvalene box

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