Recent advances in transition metal-catalyzed olefinic C–H functionalization

文献情報

出版日 2020-12-23

DOI 10.1039/D0QO01159B

インパクトファクター 5.281

著者

Bingxian Liu, Lingyun Yang, Pengfei Li, Fen Wang

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要旨

Transition metal-catalyzed directed C–H activation has emerged as an increasingly powerful tool for the synthesis of important organic building blocks, organic materials and natural products. Despite the great advances in the past decades, the majority of C–H functionalization systems focus on aryl C–H activation. Given the wide presence of alkenes as substrates, olefinic C–H functionalization, which is a step-economic process, is highly desirable for the construction of functional olefins. Herein, we summarize the recent advances during 2015–2020 in the field of metal-catalyzed olefinic C–H functionalization. This review is organized according to the metal center of the catalyst, with an emphasis on the similarities and differences among different catalysts in olefinic C–H functionalization.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry