Radical generation from electroreduction of aryl and benzyl ammonium salts: synthesis of organoboronates

文献情報

出版日 2020-12-12

DOI 10.1039/D0QO00979B

インパクトファクター 5.281

著者

Long Lin, Qianjin Chen, Bo Xu

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要旨

We report a direct electrocatalytic borylation of aryl and benzyl trimethylammonium salts with bis(pinacolato)diboron at room temperature. The protocol is compatible with substrates bearing a variety of functional groups, including halides (Cl and Br), which are not tolerated by previously reported methods involving nickel catalysis or photocatalysis. The protocol does not require stoichiometric metals, external reducing agents, or sacrificial anodes and can be carried out on a gram scale.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Radical generation from electroreduction of aryl and benzyl ammonium salts: synthesis of organoboronates

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