Organocatalytic 1,5-trifluoromethylthio-sulfonylation of vinylcyclopropane mediated by visible light in the water phase

文献情報

出版日 2020-04-24

DOI 10.1039/D0QO00343C

インパクトファクター 5.281

著者

Junkai Liu, Hong Yao, Xinnan Li, Hongyu Wu, Aijun Lin, Hequan Yao, Jinyi Xu, Shengtao Xu

原文を見る

要旨

1,2-Difunctionalization has developed into a robust tool for the preparation of complex organic molecules, and remote difunctionalization has also aroused widespread interest to achieve pluripotency of difunctionalization. Herein, we report a metal-free organocatalytic system mediated by visible light to realize the remote 1,5-trifluoromethylthio-sulfonylation of vinylcyclopropane with ArSO2SCF3 reagents in the water phase. This reaction exhibits broad functional group compatibility, moderate to good yields, and high regioselectivities and stereoselectivities.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Organocatalytic 1,5-trifluoromethylthio-sulfonylation of vinylcyclopropane mediated by visible light in the water phase

文献情報

おすすめジャーナル

関連文献

Enzymatic preparation of biotinylated naturally-occurring sialylglycan and its molecular recognition on a quartz-crystal microbalance

Carene terpenoids by gold-catalyzed cycloisomerization reactions

Gold and silver nanoparticles functionalized with known numbers of oligonucleotides per particle for DNA detection

Synthesis and structure of [{Sn(μ–PCy)}3(Na·PMDETA)2], containing an electron-deficient [{Sn(μ–PCy)}3]2− dianion

Selective growth of a less stable polymorph of 2-iodo-4-nitroaniline on a self-assembled monolayer template

A sequential highly stereoselective hydroboration and Suzuki–Miyaura cross-coupling reaction of fluoroalkylated internal acetylenes: a practical one-pot synthesis of fluoroalkylated trisubstituted alkenes

A novel catalyst with high activity for polyhydric alcohol oxidation: nanosilver/zeolite film

Electrical property and water repellency of a networked monolayer film prepared from Au nanoparticles

Formation of dimers of inclusion cryptand/paraquat complexes driven by dipole–dipole and face-to-face π-stacking interactions

Reduction of nitroaromatics to arylnitrenium ions by vinyl halide cations

こちらもおすすめ

環戊烷-1,3-二甲酸甲酯はどのように合成されますか？

4-メトキシ-1,2,3-スチアゼ-3,5-ジオンとは何ですか？

プロスタグランジンA2について「に適用される法規ガイドラインは何ですか？'

4-アミノ-1-ナフタレン sulfonic 酸についての物理化学的性質は何ですか？

N-GlcNAc-生物素を取り扱う際の実験室安全事項は何ですか？

3-アミノメチルフローラノピペリジン-1-カルボニル酸テルブチルエステルとは何ですか？

6-溴-1-甲基-1H-ベンゾ[d][1,2,3]三氮唑はどのように合成されますか？

4-硫代尿苷はどのように合成されますか？

ブレインナトリユリックペプチド32ラットとは何ですか？

1-(3-氮杂啶)-4-羟基哌啶双盐酸盐の物理化学的性質は何ですか？

掲載誌

Organic Chemistry Frontiers

おすすめ化合物

POLYGLYCERYL-3 POLYRICINOLEATE

2-(2-Aminoethyl)-1H-isoindole-1,3(2H)-dione hydrochloride (1:1)

2,5-Dichloro-3-methylthiophene

2-Nitrobenzotrifluoride

2-Ethylhexyl dihydrogen phosphate

おすすめサプライヤー