Oxygen tolerant, photoinduced controlled radical polymerization approach for the synthesis of giant amphiphiles

文献情報

出版日 2021-03-18

DOI 10.1039/D0PY01608J

インパクトファクター 5.582

著者

Alexis Theodorou, Petros Mandriotis, Athina Anastasaki, Kelly Velonia

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要旨

Amphiphilic protein–polymer conjugates form hybrid nanostructures with a broad range of potential applications. Herein, we expand the scope of amphiphilic protein–polymer bioconjugates via an oxygen tolerant, photoinduced RDRP method. A range of hydrophobic acrylic, methacrylic and acrylamide-based monomers are comprehensively screened to identify optimum reaction conditions that lead to quantitative biomacroinitiator consumption. By judiciously varying a number of components (e.g. monomer loading, catalyst concentration, pH, co-solvent, salt content), well-defined protein–polymer conjugates bearing different polymer moieties were obtained and their intrinsic properties were expressed through both their self-assembled architectures and esterase-like catalytic activity.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Oxygen tolerant, photoinduced controlled radical polymerization approach for the synthesis of giant amphiphiles

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