Copolymerisation of 1-alkenes with bulky oxygen-containing olefins for dual-stage functionalisation of polyolefins

文献情報

出版日 2020-11-18

DOI 10.1039/D0PY01303J

インパクトファクター 5.582

著者

Makoto Nakamura, Kohtaro Osakada

原文を見る

要旨

Pd–Diimine complexes catalyse the copolymerisation of 1-alkenes with olefins having a bulky oxygen-containing substituent, either 4-methyl-1-vinyl-2,6,7-trioxabicyclo[2.2.2]octane (VTO) or 2-methyl-2-vinyl-1,3-dioxolane (MVD), to afford a copolymer containing functional groups (up to 34 mol% of the total repeating units). The repeating units from VTO and MVD are mainly incorporated into the terminal of the branches and the main chain of the copolymer, respectively. Hydrolysis of the resulting copolymers by CF3COOH affords polymers with COOH or COMe substituents, which are difficult to obtain efficiently by the direct copolymerisation of acrylic acid or methyl vinyl ketone.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Copolymerisation of 1-alkenes with bulky oxygen-containing olefins for dual-stage functionalisation of polyolefins

文献情報

おすすめジャーナル

関連文献

Front cover

Principles of Fourier transform ion cyclotron resonance mass spectrometry and its application in structural biology

Disequilibrium effects in metal speciation by capillary electrophoresisinductively coupled plasma mass spectrometry (CE-ICP-MS); theory, simulations and experiments

Nitrogen rejection in natural gas using NaZSM-25 zeolite

Enhancing acid–base–water ternary aerosol nucleation with organic acid: a case of tartaric acid

The rational design of high-performance graphene-based single-atom electrocatalysts for the ORR using machine learning

Calcium selective test strip for water and milk

Electric-field frictional effects in confined zwitterionic molecules

Physicochemical insights into semiconductor properties of a semitransparent tantalum nitride photoanode for solar water splitting

Arsinothioyl-sugars produced by in vitro incubation of seaweed extract with liver cytosol analysed by HPLC coupled simultaneously to ES-MS and ICP-MS

こちらもおすすめ

S-(甲硅烷基丙基)異硫酰氯を取り扱う際の実験室安全事項は何ですか？

8-硝基-咪唑并[1,2-a]吡啶とは何ですか？

4-ブロモ-5-メトキシピリジン-2-甲醇の代替品はありますか？

全氟-1,2-二甲基環己烷を含む廃棄物はどのように処理すべきですか？

3-(溴甲基)苯乙酸の主な用途は何ですか？

5-イドキド-4-メチオキシ-6-メチルピリミジニン-2-アミンはどのように保存すればよいですか？

1-(2-溴-6-甲氧基苯基)乙酮を取り扱う際の実験室安全事項は何ですか？

5-(4,4,5,5-テトラメチル-1,3,2-ダイオキサボラロール-2-イル)-1,3-ジヒドロ-2-ベンゾフランは安全ですか？

4-溴萘-1-甲酸の代替品はありますか？

ε-白藜芦醇脱氢二聚体の代替品はありますか？

掲載誌

Polymer Chemistry

おすすめ化合物

3-Bromo-9H-carbazole

Narcissin

1,2-O-Isopropylidene-alpha-D-xylofuranose

N,N'-Bis(2,6-diisopropylphenyl)carbodiimide

Methyl 4-(bromomethyl)benzoate

おすすめサプライヤー