A rhodamine-based dual chemosensor for the naked-eye detection of Hg2+ and enhancement of the fluorescence emission for Fe3+

文献情報

出版日 2020-11-11

DOI 10.1039/D0PP00302F

インパクトファクター 0

著者

Jian-Peng Hu, Hao-Hang Yang, Qi Lin, Hong Yao, Tai-Bao Wei, Wen-Juan Qu

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要旨

A novel fluorescent chemosensor based on trimesoyl chloride–rhodamine (TR) was successfully synthesized. Rising chromogenic and fluorogenic spectral enhancements could be observed in trimesoyl chloride–rhodamine (TR) probes when Hg2+ and Fe3+ were added, respectively. TR has shown selectivity for Hg2+ and Fe3+ with high sensitivity due to metal ion complexation induced photophysical “turn-on” signaling responses. The detection limit towards Hg2+ was 2.46 × 10−8 M as determined by the 3σ method. At the same time, fluorogenic spectral enhancements were observed in TR, which exhibits a superior sensitive and selective recognition towards Fe3+ with 4.11 × 10−8 M of the detection limit. The test strips were used for colorimetric and simple detection towards Hg2+, which might finally enable the advancement of the Hg2+ sensor in the field of on-site detection.

掲載誌

Photochemical & Photobiological Sciences

CiteScore: 5.6

自己引用率: 7.4%

年間論文数: 154

Photochemical & Photobiological Sciences (PPS) is a monthly journal for the publication of original research papers (Full papers), Reviews, Perspectives, Communications and Technical notes of current interest in the areas of photochemistry and photobiology. The journal also contains a Forum section. PPS is published by Springer and is the official journal of the European Society for Photobiology (ESP) and the European Photochemistry Association (EPA). The journal publishes articles on the interaction of light with molecules, supramolecular systems or biological matter. Topics include, but are not limited to the following. Applied photochemistry Atmospheric photochemistry Bioluminescence Chronobiology DNA repair Energy transfer Environmental photobiology Environmental photochemistry Excited state properties Laser photochemistry Luminescence Mechanistic photochemistry Organic and inorganic photochemistry Photocarcinogenesis Photochemical kinetics Photochemistry of biomolecules Photochemotherapy Photochromism Photodegradation Photodermatology Photoelectrochemistry Photoimaging Photoimmunology Photomedicine Photomorphogenesis Photomovement Photoprotection Photoreception Photosensitisation Photosynthesis Phototechnology Phototherapy Phototoxicity Solar energy utilisation Spectroscopy Spectroscopy of biological systems Supramolecular photochemistry Synthetic photochemistry Theoretical photochemistry UV and visible radiation effects and vision

A rhodamine-based dual chemosensor for the naked-eye detection of Hg2+ and enhancement of the fluorescence emission for Fe3+

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