Possibility of making aerophobic surfaces by nanoprotrusions: an investigation of atomic-scale friction of the air–solid interfaces

Emerging, new atomic-scale fabrication methods have enabled scientists to design and manufacture nanostructured devices for the investigation and application of nanoscale regimes in fluid mechanics. One of the most significant goals in designing these devices is finding an efficient way to reduce the friction of the fluid flow in/on the nanochannels and surfaces. Herein, a set of surfaces with various engineered nanoscale roughnesses (nanoprotrusions) was designed. In addition, a triple point charge/mass model of air molecules was developed based on realistic physicochemical characteristics. All-atom, non-equilibrium molecular dynamics simulations were employed to evaluate the atomic interaction of airflow/solid surfaces for various conditions, such as different fluid velocity, surface material, and geometry of nanoscale roughness. Our results show that there is a significant difference (more than six times) between the fluid/surface interaction energy for graphene and silicone surfaces. However, the interaction energy of the fluid/solid interface does not vary for atomic-scale roughnesses (<10 nm). Our results indicate that for solid surfaces coated by few-layer graphene in high Reynolds (supersonic) regimes, the outer graphene layers are confronted with delamination due to the high shear stress of airflow, which is a serious problem for the structure's strength and durability. We suggest that our computational findings shed light on designing aerophobic surface coatings in a wide range of applications, from nanodevices to conventional aircraft.