Masking specific effects of ionic liquid constituents at the solid–liquid interface by surface functionalization

文献情報

出版日 2020-10-19

DOI 10.1039/D0CP02805C

インパクトファクター 3.676

著者

Bojana Katana, Dóra Takács, Felix D. Bobbink, Paul J. Dyson, Nizar B. Alsharif, Matija Tomšič, Istvan Szilagyi

原文を見る

要旨

Ion specific effects of ionic liquid (IL) constituents on the surface charge and aggregation properties of two types of particles (positively charged amidine (AL) and polyimidazolium-functionalized sulfate (SL-IP-2) latexes) were investigated in IL solutions containing different anions and the 1-butyl-3-methylimidazolium cation. For the AL systems, the affinity of IL anions to the particle surface followed the sequence chloride < bromide < nitrate < acetate. The critical coagulation concentration values decreased in the same order indicating that ion specific adsorption determines the surface charge density and the extent of the repulsive interparticle forces. In contrast, no tendencies were observed for the SL-IP-2 particles, i.e., both charge and aggregation features were insensitive to the type of anions. This surprising behavior sheds light on that surface functionalization with the polyimidazolium compound effectively masks interfacial ion specific effects. These results indicate new possible routes to the design of processable particle dispersions in ILs irrespective of their composition.

掲載誌

Physical Chemistry Chemical Physics

CiteScore: 5.5

自己引用率: 10.3%

年間論文数: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.