Interparticle distance as a key factor for controlling the dual-emission properties of carbon dots

文献情報

出版日 2020-06-25

DOI 10.1039/D0CP02120B

インパクトファクター 3.676

著者

Hyo Jeong Yoo, Byeong Eun Kwak, Do Hyun Kim

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要旨

Due to their distinct and useful features, multi-color-emissive carbon dots (CDs) have gained much attention, however, their lack of red emission has so far limited their practical use for various applications, thus understanding of their emission origins is required. Concentration-dependent photoluminescence (PL) is a unique feature of CDs and is regarded as one way to realize tunable PL, providing information on their PL mechanism. In this work, we synthesized concentration-dependent blue/red dual-color-emissive CDs under single excitation at 365 nm. With the increase in concentration, the blue emission band showed a large red-shift from 431 to 500 nm, while the red emission band at around 650 nm showed only a relative intensity change, without a significant spectral shift. We performed spectroscopic analysis by changing the solution environment including the solvent type and pH to investigate the origins of the two emission bands. These results, combined with the zeta potential and fluorescence microscopy results, confirmed that the interparticle distance of CDs is a key factor for their dual-emissive PL behavior. With the advantage of unique PL features, we showed the potential of the CDs for white light-emitting diode (WLED) and ratiometric pH sensing applications.

掲載誌

Physical Chemistry Chemical Physics

CiteScore: 5.5

自己引用率: 10.3%

年間論文数: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.