Solvent-controlled assembly of pillar[5]arene-based supramolecular networks via π–π interactions for white light modulation

文献情報

出版日 2019-12-13

DOI 10.1039/C9QO01383K

インパクトファクター 5.281

著者

Qi Li, Yuezhou Liu, Peiren Liu, Liqing Shangguan, Huangtianzhi Zhu, Bingbing Shi

原文を見る

要旨

White light emitting materials have gained considerable attention. Exploring new strategies to achieve controllable white light emission is important for the construction and application of fluorescent materials. Here we report a supramolecular network based on pyrene-containing pillar[5]arene via π–π interactions, whose assembly and emission are controlled by solvent polarity. By introducing a red emissive europium complex guest, we successfully fabricate a supramolecular crosslinked network with solvent polarity-dependent emissions. White light emission with a CIE coordinate at (0.33, 0.31) is also achieved by adjusting the methanol fraction. This work provides a method to construct tunable fluorescent supramolecular systems and generate homogeneous white light emission by controlling noncovalent interactions.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Solvent-controlled assembly of pillar[5]arene-based supramolecular networks via π–π interactions for white light modulation

文献情報

おすすめジャーナル

関連文献

Efficient immobilisation of Rh-MonoPhos on the aluminosilicate AlTUD-1

Palladium catalysed cyclisation–carbonylation of enynes to give cyclic γ,δ-unsaturated acids

Electrical property and water repellency of a networked monolayer film prepared from Au nanoparticles

Modified micro-space using self-organized nanoparticles for reduction of methylene blue

A novel migrative addition reaction of hydrazines to the diketone derivative of C60

Synthesis and structure of [{Sn(μ–PCy)}3(Na·PMDETA)2], containing an electron-deficient [{Sn(μ–PCy)}3]2− dianion

Facile protocol for the highly regioselective and stereodivergent synthesis of substituted bishomoallylic alcohols from esters

A neutral self-assembled coordination cage organized for inclusion of aromatic guests

A sequential highly stereoselective hydroboration and Suzuki–Miyaura cross-coupling reaction of fluoroalkylated internal acetylenes: a practical one-pot synthesis of fluoroalkylated trisubstituted alkenes

Synthesis and characterization of a benzene-centered, phthalocyanine hexamer

こちらもおすすめ

環戊烷-1,3-二甲酸甲酯はどのように合成されますか？

4-メトキシ-1,2,3-スチアゼ-3,5-ジオンとは何ですか？

プロスタグランジンA2について「に適用される法規ガイドラインは何ですか？'

4-アミノ-1-ナフタレン sulfonic 酸についての物理化学的性質は何ですか？

N-GlcNAc-生物素を取り扱う際の実験室安全事項は何ですか？

3-アミノメチルフローラノピペリジン-1-カルボニル酸テルブチルエステルとは何ですか？

6-溴-1-甲基-1H-ベンゾ[d][1,2,3]三氮唑はどのように合成されますか？

4-硫代尿苷はどのように合成されますか？

ブレインナトリユリックペプチド32ラットとは何ですか？

1-(3-氮杂啶)-4-羟基哌啶双盐酸盐の物理化学的性質は何ですか？

掲載誌

Organic Chemistry Frontiers

おすすめ化合物

4-Bromoheptane

N-[(1S,2R,4S)-2-Amino-4-(dimethylcarbamoyl)cyclohexyl]-N'-(5-chloro-2-pyridinyl)ethanediamide

5,7,8'-Trihydroxy-2',2'-dimethyl-2'H,4H-3,6'-bichromen-4-one

Ethyl 4-cyanobenzoate

2,5-Dichloro-3-methylthiophene

おすすめサプライヤー