PhI(OAc)2-mediated oxidative rearrangement of allylic amides: efficient synthesis of oxazoles and β-keto amides

文献情報

出版日 2019-11-15

DOI 10.1039/C9QO01298B

インパクトファクター 5.281

著者

Kang Xu, Shuang Yang, Zhenhua Ding

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要旨

A series of 2,5-disubstituted oxazoles and β-keto amides were synthesized from allylic amides via PhI(OAc)2-mediated intramolecular cyclization and oxidation with the migration of an aryl group. These reactions were performed under mild conditions with good functional group tolerance and gave the corresponding products in good to excellent yields.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

PhI(OAc)2-mediated oxidative rearrangement of allylic amides: efficient synthesis of oxazoles and β-keto amides

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