Practical fluorothiolation and difluorothiolation of alkenes using pyridine-HF and N-thiosuccinimides

文献情報

出版日 2019-11-22

DOI 10.1039/C9QO01228A

インパクトファクター 5.281

著者

Xiaojun Zeng, Bo Xu

原文を見る

要旨

We have developed highly efficient fluorothiolation and difluorothiolation of alkenes under simple and mild conditions. Our fluorothiolation reagents are the commercially available Olah's reagent (Py-HF) and readily available N-thiosuccinimides. This transition metal-free system offers good chemical yields for a wide range of alkene substrates with excellent regioselectivity and good functional group tolerance.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Practical fluorothiolation and difluorothiolation of alkenes using pyridine-HF and N-thiosuccinimides

文献情報

おすすめジャーナル

関連文献

Synthesis and structure of [{Sn(μ–PCy)}3(Na·PMDETA)2], containing an electron-deficient [{Sn(μ–PCy)}3]2− dianion

From atactic to isotactic CO/p-methylstyrenecopolymer by proper modification of Pd(ii) catalysts bearing achiral α-diimines

Trimethyltriazacyclohexane as bridging ligand for triangular Cu3 units and C–H hydride abstraction into a Cu6 cluster

Supramolecular control of complexation-induced fluorescence change of water-soluble, β-cyclodextrin-modified CdS quantum dots

Efficient immobilisation of Rh-MonoPhos on the aluminosilicate AlTUD-1

Electrical property and water repellency of a networked monolayer film prepared from Au nanoparticles

Influence of substrate on self-assembled photonic crystal

Reactivity of a N-heterocyclic carbene, 1,3-di-(1-adamantyl) imidazol-2-ylidene, with a pseudo-acid: structural characterization of Claisen condensation adduct

Selective formation of siloxane-based hybrid cages with methylene groups in the frameworks

Synthesis of novel starburst and dendritic polyhedral oligosilsesquioxanes

こちらもおすすめ

環戊烷-1,3-二甲酸甲酯はどのように合成されますか？

4-メトキシ-1,2,3-スチアゼ-3,5-ジオンとは何ですか？

プロスタグランジンA2について「に適用される法規ガイドラインは何ですか？'

4-アミノ-1-ナフタレン sulfonic 酸についての物理化学的性質は何ですか？

N-GlcNAc-生物素を取り扱う際の実験室安全事項は何ですか？

3-アミノメチルフローラノピペリジン-1-カルボニル酸テルブチルエステルとは何ですか？

6-溴-1-甲基-1H-ベンゾ[d][1,2,3]三氮唑はどのように合成されますか？

4-硫代尿苷はどのように合成されますか？

ブレインナトリユリックペプチド32ラットとは何ですか？

1-(3-氮杂啶)-4-羟基哌啶双盐酸盐の物理化学的性質は何ですか？

掲載誌

Organic Chemistry Frontiers

おすすめ化合物

N-[(5,6-Dichloro-1H-benzimidazol-2-yl)methyl]-9-(1-methyl-1H-pyrazol-4-yl)-2-(4-morpholinyl)-9H-purin-6-amine

2-Nitrobenzotrifluoride

Ethyl 4-cyanobenzoate

5,7,8'-Trihydroxy-2',2'-dimethyl-2'H,4H-3,6'-bichromen-4-one

N-[(9H-Fluoren-9-ylmethoxy)carbonyl]-beta-phenyl-L-phenylalanine

おすすめサプライヤー