Guest-length driven high fidelity self-sorting in supramolecular capsule formation of calix[5]arenes in water

文献情報

出版日 2019-10-14

DOI 10.1039/C9QO01188A

インパクトファクター 5.281

著者

Ilenia Pisagatti, Lucia Barbera, Giuseppe Gattuso, Melchiorre F. Parisi, Silvano Geremia, Neal Hickey, Anna Notti

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要旨

A four component system consisting of two water-soluble calix[5]arenes (1 and 2) with differently substituted upper-rims and two α,ω-alkanediyldiammonium ions of different lengths (NC8N and NC10N) was found to assemble in a high-fidelity fashion providing exclusively the two homocalixarene capsules 1⊃NC8N⊂1 and 2⊃NC10N⊂2, irrespective of the order of guest addition. When the longer linker (NC10N) was left out from the mixture altogether, however, 1⊃NC8N⊂2 heterocapsules were formed.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Guest-length driven high fidelity self-sorting in supramolecular capsule formation of calix[5]arenes in water

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