Diastereoselective formal [3 + 3] cycloaddition of isatin-based α-(trifluoromethyl)imines with N,N′-dialkyloxyureas

文献情報

出版日 2019-10-21

DOI 10.1039/C9QO01181A

インパクトファクター 5.281

著者

Hong-Wu Zhao, Jia-Ming Guo, Li-Ru Wang, Wan-Qiu Ding, Zhe Tang, Xiu-Qing Song, Hui-Hui Wu, Xiao-Zu Fan, Xiao-Fan Bi

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要旨

In the presence of PhI(OH)(OTs) and NaH, the diastereoselective formal [3 + 3] cycloaddition of isatin-based α-(trifluoromethyl)imines with N,N′-dialkyloxyureas proceeded readily, and furnished the relatively trans-configured novel spiro-1,3,5-triazinan-2-ones in reasonable chemical yields. The relative stereochemical configuration of the target products was clearly identified by X-ray diffraction analysis.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Diastereoselective formal [3 + 3] cycloaddition of isatin-based α-(trifluoromethyl)imines with N,N′-dialkyloxyureas

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