Rhodium-catalyzed biheteroaryl-2-carbonitrile synthesis via double C–H activation

文献情報

出版日 2019-10-16

DOI 10.1039/C9QO01114E

インパクトファクター 5.281

著者

Hui-Bei Xu, Yan-Ying Zhu, Jia-Hui Yang, Xin-Yue Chai, Lin Dong

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要旨

Rhodium(III)-catalyzed double C–H activation and in situ dealcoholization to generate useful biheteroaryl-2-carbonitriles have been well developed via a CDC mechanism, in which benzimidates act as both directing groups and the precursors of nitrile groups. This simple and atom-economical method synthesizes various biheteroaryl-2-carbonitrile derivatives, which could be further transformed to more complex compounds.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Rhodium-catalyzed biheteroaryl-2-carbonitrile synthesis via double C–H activation

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