Chiral-at-metal rhodium(iii) complex catalyzed enantioselective synthesis of C2-substituted benzofuran derivatives

文献情報

出版日 2019-09-18

DOI 10.1039/C9QO01022J

インパクトファクター 5.281

著者

Qiang Kang, Yu Du

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要旨

A highly efficient enantioselective C2-nucleophilic functionalization of 3-aminobenzofurans with α,β-unsaturated carbonyl compounds has been realized under catalysis of chiral-at-metal rhodium(III) complexes, affording a large array of potentially bioactive C2-substituted benzofuran derivatives with high yields (76–99%) and enantioselectivities (up to 98% ee).

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Chiral-at-metal rhodium(iii) complex catalyzed enantioselective synthesis of C2-substituted benzofuran derivatives

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