Solvent-controlled chemoselective N-dealkylation-N-nitrosation or C-nitration of N-alkyl anilines with tert-butyl nitrite

文献情報

出版日 2019-08-21

DOI 10.1039/C9QO00965E

インパクトファクター 5.281

著者

Qaiser Mahmood, Guangqiang Xu, Qinggang Wang

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要旨

A metal-free, acid-free and chemoselective N-dealkylation-N-nitrosation or C-nitration of N-alkyl anilines has been developed. tert-Butyl nitrite (TBN) efficiently promotes the synthesis of N-nitrosoanilines, nitroanilines and N-nitroso-nitroanilines with good to excellent yields and chemoselectivities. The selective reduction of N-nitrosoanilines and N-nitroso-nitroanilines was smoothly achieved, affording phenylhydrazine, 2-nitroaniline and 1,2-benzenediamine derivatives.

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Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Solvent-controlled chemoselective N-dealkylation-N-nitrosation or C-nitration of N-alkyl anilines with tert-butyl nitrite

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