C(sp3)–H hydroxylation of fluorenes, oxindoles and benzofuranones with a Mg(NO3)2–HP(O)Ph2 oxidation system

文献情報

出版日 2019-07-19

DOI 10.1039/C9QO00778D

インパクトファクター 5.281

著者

Chen Hu, Gang Hong, Pradip D. Nahide, Yuchen He, Chen Zhou, Marisa C. Kozlowski, Limin Wang

原文を見る

要旨

A novel oxidation system in which magnesium nitrate [Mg(NO3)2] is used as an oxidant in the presence of diphenylphosphine oxide [HP(O)Ph2] permits the C(sp3)–H hydroxylation of fluorenes, oxindoles, and benzofuranones. This method features high efficiency, good functional group tolerance, and operational simplicity. Its synthetic utility is highlighted by further transformations to valuable organic materials.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

C(sp3)–H hydroxylation of fluorenes, oxindoles and benzofuranones with a Mg(NO3)2–HP(O)Ph2 oxidation system

文献情報

おすすめジャーナル

関連文献

The infrared spectra of protic ionic liquids: performances of different computational models to predict hydrogen bonds and conformer evolution

Pyridine–acetaldehyde, a molecular balance to explore the n→π* interaction

Graphyne-anchored single Fe atoms as efficient CO oxidation catalysts as predicted by DFT calculations

Phase transition and electronic properties of skutterudite-type IrP3 under high pressure

Abnormal scaling of excitons in phosphorene quantum dots

Adsorption of H2 on amorphous solid water studied with molecular dynamics simulations

Dynamics of propene and propane in ZIF-8 probed by solid-state 2H NMR

Molecular dynamics simulation of thermo-mechanical behaviour of elastomer cross-linked via multifunctional zwitterions

Two-dimensional infrared spectroscopy from the gas to liquid phase: density dependent J-scrambling, vibrational relaxation, and the onset of liquid character

Sodium-assisted passivation of grain boundaries and defects in Cu2ZnSnSe4 thin films

こちらもおすすめ

3-(2-オキサプロピル)ベンzoic酸はどのように合成されますか？

BOC-L-3-氟苯丙氨酸の主な用途は何ですか？

4-メチル-4-ピペリジニル-1-ピロリドイン甲酸の主な用途は何ですか？

Biotin-PEG3-oxyamine HCl塩について、適切な化合物名称に適用される法規ガイドラインは何ですか？

N-(4-イソチオシアネートフェニル)-2-メトキシアリニンはどのように合成されますか？

金粉蕨亭2'-O-葡萄糖甙の主な用途は何ですか？

2-(2-ニトロフェニル)酢酸ヒドライドの物理化学的性質は何ですか？

5-(ヒドロキシメチル)-2-チオキソ-2,3-ジヒドロピリミジン-4(1H)-オンを取り扱う際の実験室安全事項は何ですか？

11-脱氢血栓烷 b2の市場動向や研究トレンドはどうですか？

3,3-二甲基哌啶-4-酮はどのように保存すればよいですか？

掲載誌

Organic Chemistry Frontiers

おすすめ化合物

4-Iodopentylbenzene

2-[({[(2-Methyl-2-propanyl)oxy]carbonyl}amino)methyl]isonicotinic acid

Selenoxomercury

[4-Chloro-3-(diethylcarbamoyl)phenyl]boronic acid

Chloro(methyldiphenylphosphine)gold(I)

おすすめサプライヤー