Using light to control the inhibition of Karstedt's catalyst

文献情報

出版日 2019-03-26

DOI 10.1039/C9QO00221A

インパクトファクター 5.281

著者

Brahmjot Kaur, Rameez Raza, Mitchell J. Stashick, Neil R. Branda

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要旨

Hydrosilylation reactions are commonly used in the coating industry but the high activity of the platinum catalysts diminishes the ‘pot life’ of the reagents, and poses a serious industrial problem. In this communication, we illustrate a method for controlling the activity of these catalysts by using light as an external stimulant to turn ‘off’ a small molecule inhibitor, and activate the catalyst.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Using light to control the inhibition of Karstedt's catalyst

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