Synthesis, photophysical properties, and self-dimerization studies of 2-λ5-phosphaquinolin-2-ones

文献情報

出版日 2019-03-25

DOI 10.1039/C9QO00199A

インパクトファクター 5.281

著者

Jeremy P. Bard, Chun-Lin Deng, Hannah C. Richardson, Jacob M. Odulio, Joshua E. Barker, Lev N. Zakharov, Paul H.-Y. Cheong, Darren W. Johnson, Michael M. Haley

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要旨

We have rationally designed and synthesized a library of phosphaquinolinone derivatives containing various electron-donating and -withdrawing groups on two positions of the scaffold. Distinct trends are observed between the substituents on R1 and R2 with both the photophysical properties of the molecules and their dimerization strengths. With withdrawing groups upon the scaffold, dimerization constants surpass 500 M−1 in H2O-saturated CDCl3. Computational studies on the dimeric structures corroborate the experimental findings.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Synthesis, photophysical properties, and self-dimerization studies of 2-λ5-phosphaquinolin-2-ones

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