Synthesis of an open-cage fullerene-based unidirectional H-bonding network and its coordination with titanium

文献情報

出版日 2019-03-05

DOI 10.1039/C9QO00188C

インパクトファクター 5.281

著者

Hao Zhang, Jie Su, Changwang Pan, Xing Lu

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要旨

Open-cage fullerene derivatives with up to three hydroxyl groups on the rim of an orifice were prepared through modification of functional groups followed by controlled stepwise reduction of carbonyl groups on the rim. The hydroxyl groups form a unidirectional H-bond network and show a weak but clear interaction with a water molecule trapped inside the fullerene cage. Titanium ions coordinated with the hydroxyl and carbonyl groups to form a TiL2 type of complex.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Synthesis of an open-cage fullerene-based unidirectional H-bonding network and its coordination with titanium

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