Copper-catalyzed direct C–H phosphorylation of N-imino isoquinolinium ylides with H-phosphonates

文献情報

出版日 2019-03-15

DOI 10.1039/C9QO00107G

インパクトファクター 5.281

著者

Xin-Chen Zhan, Yu-Yuan Hei, Jian-Lan Song, Peng-Cheng Qian, Xing-Guo Zhang, Chen-Liang Deng

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要旨

A new and efficient protocol for the synthesis of phosphorus-containing isoquinoline skeletons via copper-catalyzed direct C–H phosphorylation of N-iminoisoquinolinium ylides with H-phosphonates has been described. A variety of N-iminoisoquinolinium ylides reacted under the ligand and oxidant free conditions smoothly to afford phosphorylated isoquinolines in moderate to excellent yields.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Copper-catalyzed direct C–H phosphorylation of N-imino isoquinolinium ylides with H-phosphonates

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