Cu(ii)- or Co(ii)-Catalyzed C(SP3)–H oxidation of N,N-dimethylaminoethanol: facile synthesis of methylene-bridged biindoles and 3-formylindoles selectively

文献情報

出版日 2019-03-01

DOI 10.1039/C9QO00097F

インパクトファクター 5.281

著者

Robert C. Hider

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要旨

Methylene-bridged biindoles and 3-formylindoles were selectively synthesized using a new carbon donor N,N-dimethylethanolamine, catalyzed by CuCl2 and CoCl2 respectively. A high conversion rate and good regioselectivity were achieved. Oxygen atmosphere promoted the reaction toward the conversion of 3-formylindoles.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Cu(ii)- or Co(ii)-Catalyzed C(SP3)–H oxidation of N,N-dimethylaminoethanol: facile synthesis of methylene-bridged biindoles and 3-formylindoles selectively

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