Photoinduced free radical promoted cationic polymerization 40 years after its discovery

文献情報

出版日 2019-12-30

DOI 10.1039/C9PY01903K

インパクトファクター 5.582

著者

Mehmet Atilla Tasdelen, Jacques Lalevée, Yusuf Yagci

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要旨

This perspective article is prepared in the memory of Anthony Ledwith who discovered Free Radical Promoted Cationic Polymerization (FRPCP) as a versatile photoinitiating system for cationic polymerization about four decades ago. Mechanistically, distinct modes for the photochemical formation of electron donor radicals in the UV, Vis and NIR range that can be oxidized to reactive cations to initiate the cationic polymerization of oxiranes and vinyl monomers are discussed. The dual polymerization strategies that have been applied to combine FRPCP with the other modes of polymerization processes are presented.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

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Photoinduced free radical promoted cationic polymerization 40 years after its discovery

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