A hydrate salt-promoted reductive coupling reaction of nitrodienes with unactivated alkenes

文献情報

出版日 2019-01-31

DOI 10.1039/C9OB00136K

インパクトファクター 3.876

著者

Mengmeng Zhang, Liming Yang, Chao Tian, Meng Zhou, Guangming Li

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要旨

Transition metal-catalyzed reductive coupling has emerged as a powerful method for the construction of C–C bonds. Herein, a crystalline hydrate, Na2HPO4·7H2O, has been disclosed as an effective promoter for the reductive coupling of nitrodienes with unactivated alkenes to afford diverse dienes with various functionalities in an open-flask manner. The mechanism study has revealed that Na2HPO4·7H2O accelerates the in situ generation of active silane PhSi(OEt)H2 and prevents the deactivation of catalyst. The approach can increase the efficiency of previous reductive coupling reactions as well.

掲載誌

Organic & Biomolecular Chemistry

CiteScore: 3.4

自己引用率: 10.3%

年間論文数: 1041

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.

A hydrate salt-promoted reductive coupling reaction of nitrodienes with unactivated alkenes

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