Structural characterization of molybdenum–dinitrogen complex as key species toward ammonia formation by dispersive XAFS spectroscopy

文献情報

出版日 2020-04-23

DOI 10.1039/C9CP06761B

インパクトファクター 3.676

著者

Kazuya Arashiba, Shimpei Naniwa, Kazuo Kato, Hiromasa Tanaka, Kazunari Yoshizawa, Yoshiaki Nishibayashi

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要旨

The structural characterization of a hardly-isolatable molybdenum–dinitrogen complex bearing a PNP-type pincer ligand, which is assumed to be a key reactive complex in the stoichiometric transformation of a molybdenum triiodide complex [MoI3(PNP)] into the corresponding molybdenum nitride complex under an atmospheric pressure of dinitrogen, was carried out by using dispersive XAFS.

掲載誌

Physical Chemistry Chemical Physics

CiteScore: 5.5

自己引用率: 10.3%

年間論文数: 3036

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