1,2-Amino alcohol-dependent Petasis allylboration for racemic and chiral homoallylamines

文献情報

出版日 2019-01-30

DOI 10.1039/C8QO01428K

インパクトファクター 5.281

著者

Zi-Wei Lin, Yang Zhou, Zhen-Ni Zhao, Yan Zhao, Jun Liu, Yi-Yong Huang

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要旨

Petasis allylboration among an aldehyde, 1,2-amino alcohol and pinacolallylboronate has been successfully accomplished at room temperature without any catalysts. A proposed reaction pathway involving the allylboration of an in situ-generated imine through a six-membered chairlike transition state is suggested to understand the role of a positioned hydroxy group and the diastereoselective outcome.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

1,2-Amino alcohol-dependent Petasis allylboration for racemic and chiral homoallylamines

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