Carbene-catalyzed oxidative acylation promoted by an unprecedented oxidant CCl3CN

文献情報

出版日 2019-01-25

DOI 10.1039/C8QO01420E

インパクトファクター 5.281

著者

Zijun Wu, Di Jiang, Jian Wang

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要旨

An unprecedented example of a NHC-catalyzed acylation reaction promoted by an oxidant CCl3CN is described. This protocol features several advantages, including mild reaction conditions, broad substrate scope, and easy operation. In addition, low cost, low boiling point, and small molecular weight allow CCl3CN to be an attractive and amenable oxidant. Meanwhile, this formal dehydrogenative coupling reaction of aldehydes and alcohols involves a hydride transfer process.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Carbene-catalyzed oxidative acylation promoted by an unprecedented oxidant CCl3CN

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