One-step access to N-enoxyimides by gold-catalysed addition of N-hydroxyimides to terminal alkynes

文献情報

出版日 2018-12-06

DOI 10.1039/C8QO01179F

インパクトファクター 5.281

著者

Coralie Duchemin, Nicolai Cramer

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要旨

N-Enoxyimides have become attractive substrates for novel catalytic transformations, yet their tedious multi-step synthesis hampers full exploitation of their synthetic potential. We report a gold(I)-catalyzed protocol to access N-enoxyimides from simple and widely available terminal alkynes and the corresponding N-hydroxyimides in a single step. The transformation proceeds with aryl-, alkenyl- and alkyl alkynes, facilitating further studies of this substrate class in C–H functionalizations and photocatalysis.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

One-step access to N-enoxyimides by gold-catalysed addition of N-hydroxyimides to terminal alkynes

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