Synergistic effect of the Pd–Ni bimetal/carbon nanofiber composite catalyst in Suzuki coupling reaction

文献情報

出版日 2018-12-10

DOI 10.1039/C8QO01100A

インパクトファクター 5.281

著者

Guangyang Bao, Jie Bai, Chunping Li

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要旨

The palladium-catalyzed Suzuki coupling reaction is one of the most efficient strategies for constructing a carbon–carbon bond. In recent years, bimetallic catalysts have become candidates for the Suzuki coupling reaction. In this work, palladium–nickel without any ligands was successfully loaded on carbon nanofibers as a kind of bimetallic catalyst for the Suzuki coupling reaction. Introducing nickel atoms into the catalyst not only decreased the preparation cost but also enhanced the catalytic ability due to the synergistic effect of Pd and Ni. The Pd1Ni4/CNF shows stable catalytic activity and could be reused ten times. Possible mechanisms are also proposed.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Synergistic effect of the Pd–Ni bimetal/carbon nanofiber composite catalyst in Suzuki coupling reaction

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