Manganese(iii)-mediated selective phosphorylation of enamides: direct synthesis of β-phosphoryl enamides

文献情報

出版日 2018-12-12

DOI 10.1039/C8QO01098F

インパクトファクター 5.281

著者

Dong-Liang Zhang, Cheng-Kun Li, Run-Sheng Zeng, Adedamola Shoberu, Jian-Ping Zou

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要旨

A simple and direct method for the preparation of β-phosphoryl enamides has been achieved through Mn(III)-mediated radical oxidative selective phosphorylation of N-styrylamides. The reaction could be efficiently scaled-up and the products could be easily transformed into β-amino phosphonic acid, a bio-isostere of the corresponding amino acid.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Manganese(iii)-mediated selective phosphorylation of enamides: direct synthesis of β-phosphoryl enamides

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