Reductive cleavage of the N–O bond: elemental sulfur-mediated conversion of N-alkoxyamides to amides

文献情報

出版日 2018-12-14

DOI 10.1039/C8QO01052H

インパクトファクター 5.281

著者

Senlin Wang, Xue Zhao, Daisy Zhang-Negrerie

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要旨

By treating with elemental sulfur in the presence of DABCO in DMSO, a variety of N-alkoxyamides were readily converted to amides in satisfactory to excellent yields via a metal-free reductive cleavage of the N–O bond. The mechanism of the reaction has been proposed based on the results of the control experiments, suggesting a process of cleavage of the N–O bond mediated by elemental sulfur, as well as the role played by DMSO in forming the amide in the product.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Reductive cleavage of the N–O bond: elemental sulfur-mediated conversion of N-alkoxyamides to amides

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