Copper-catalyzed direct trifluoromethylthiolation of indoles by tert-butyl 2-((trifluoromethyl)sulfonyl)hydrazine-1-carboxylate

文献情報

出版日 2018-09-15

DOI 10.1039/C8QO00779A

インパクトファクター 5.281

著者

Kui Lu, Quan Li, Xiaolan Xi, Yuna Huang, Zhi Gong, Peng Yu, Xia Zhao

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要旨

In this study, we developed the first copper-catalyzed direct trifluoromethylthiolation of indoles using TfNHNHBoc as a trifluoromethylthiolation reagent. Due to the cheap and readily accessible reagents, as well as its mild reaction conditions and good atom economy, this method is as an alternative and practical strategy for trifluoromethylthiolation of indoles.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Copper-catalyzed direct trifluoromethylthiolation of indoles by tert-butyl 2-((trifluoromethyl)sulfonyl)hydrazine-1-carboxylate

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