Palladium-catalyzed carbonylation of thioacetates and aryl iodides for the synthesis of S-aryl thioesters

文献情報

出版日 2018-07-04

DOI 10.1039/C8QO00466H

インパクトファクター 5.281

著者

Myungjin Kim, Subeen Yu, Jeung Gon Kim, Sunwoo Lee

原文を見る

要旨

Thioesters were synthesized via palladium-catalyzed carbonylation of thioacetates and aryl iodides. S-Aryl thioacetates coupled with carbon monoxide and aryl iodides to afford the desired S-aryl thioesters in good yields. The reaction showed good functional group tolerance toward fluoro, chloro, ketone, ester, aldehyde, cyano, and nitro groups. The tandem reaction of the direct S-arylation of aryl iodides from potassium thioacetate (KSAc) and subsequent carbonylation of the intermediates S-aryl thioacetates provided S-aryl thioesters in moderate-to-good yields.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Palladium-catalyzed carbonylation of thioacetates and aryl iodides for the synthesis of S-aryl thioesters

文献情報

おすすめジャーナル

関連文献

An oxygen pumping anode for electrowinning aluminium

Front cover

Experimental evidence for surface freezing in supercooled n-alkane nanodroplets

Azidoacetylene – interpretation of gas phase infrared spectra based on high-level vibrational configuration interaction calculations

A novel method for automatic single molecule tracking of blinking molecules at low intensities

Recovering degraded quasi-solid-state dye-sensitized solar cells by applying electrical pulses

Small-angle water reorientations in KOH doped hexagonal ice and clathrate hydrates

Measurement of the interface tension of smectic membranes in water

On the signature of the hydrophobic effect at a single molecule level

Nature of proton transport in a water-filled carbon nanotube and in liquid water

こちらもおすすめ

3-イチチルビフェニルはどのように合成されますか？

8-溴-5-三氟甲基喹啉はどのように合成されますか？

ジメチル4-(4,4,5,5-テトラメチル-1,3,2-ドioxaborolan-2-基)-2,6-ピリジンジカルボイル酸フェニルアミニドの代替品はありますか？

N-(3,5-ヘキサクロロ-4-ピリドインイル)-8-メチオキシ-5-キノリンカーボン酸の市場動向や研究トレンドはどのようなものでしょうか？

イソステアロイルグリセリルは安全ですか？

1-(二苯甲基)-3,3-二氟-氮杂环丁烷の市場動向や研究トレンドはどうですか？

3-チオフェンスチオールの物理化学的性質は何ですか？

2-Methyl-2-propanyl (2S)-2-(aminomethyl)-1-piperidinecarboxylateは安全ですか？

CAS番号1316822-90-8の化合物は安全ですか？

Tert-butyl 2-(2-羟基乙基)哌嗪-1-羧酸はどのように保存すればよいですか？

掲載誌

Organic Chemistry Frontiers

おすすめ化合物

PS 1145 Dihydrochloride

5'-Fluoro-[2,3'-biindolinylidene]-2',3-dione

1-{3-[4-Amino-3-(4-phenoxyphenyl)-1H-pyrazolo[3,4-d]pyrimidin-1-yl]-1-piperidinyl}-2,3-dihydroxy-1-propanone

N-{[(2-Methyl-2-propanyl)oxy]carbonyl}-L-methionylglycine

(2R)-2-(3-Bromophenyl)pyrrolidine hydrochloride (1:1)

おすすめサプライヤー