Dirhodium(ii)-catalyzed ortho C–H amination of sterically congested N,N-dialkylanilines

文献情報

出版日 2018-09-12

DOI 10.1039/C8OB01974F

インパクトファクター 3.876

著者

Motoki Ito, Tomoya Nakagawa, Kazuhiro Higuchi, Shigeo Sugiyama

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要旨

Dirhodium(II)-catalyzed ortho C–H amination of N,N-dialkylanilines has been developed. Sterically congested 1,2-diaminobenzenes were obtained in high yields with excellent chemo- and regioselectivities from para-substituted anilines and even from para-unsubstituted anilines. The ortho selectivity observed was rationalized in terms of the interaction between the dialkylamino group and a Rh(II)–nitrene intermediate.

掲載誌

Organic & Biomolecular Chemistry

CiteScore: 3.4

自己引用率: 10.3%

年間論文数: 1041

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.

Dirhodium(ii)-catalyzed ortho C–H amination of sterically congested N,N-dialkylanilines

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