X-Ray structure and ionic conductivity studies of anhydrous and hydrated choline chloride and oxalic acid deep eutectic solvents

文献情報

出版日 2018-11-26

DOI 10.1039/C8CP06728G

インパクトファクター 3.676

著者

Lorenzo Gontrani, Matteo Bonomo, Natalia V. Plechkova, Danilo Dini, Ruggero Caminiti

原文を見る

要旨

In this study, we report the structural, thermodynamic and electrochemical properties of deep eutectic solvents (DESs) formed from choline chloride and oxalic acid in anhydrous and di-hydrated form in a 1 : 1 molar ratio. As far as we are aware, this is the first joint X-ray diffraction–molecular dynamics study focussed on analyzing the structural features of DESs.

掲載誌

Physical Chemistry Chemical Physics

CiteScore: 5.5

自己引用率: 10.3%

年間論文数: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.