A thermostated cell for electrochemistry: minimising natural convection and investigating the role of evaporation and radiation
文献情報
Xiuting Li, Christopher Batchelor-McAuley, Javor K. Novev, Richard G. Compton
An optimised thermostated electrochemical cell is designed and implemented. This is informed by experimental and computational studies characterizing the extent to which the thermostating of an electrochemical cell via a heated bath can be realised, both with the cell closed and open to the environment. The heat transfer in the system is simulated and probed experimentally; special emphasis is put on heat loss due to radiation and evaporation. Experiments and simulations demonstrate that these two mechanisms of heat transfer lead to a steady temperature in the cell that differs from that of the thermostat by ∼0.1 K. Simulations indicate that spatial inhomogeneities in the stationary temperature drive natural convective flows with a significant velocity. These new physical insights inform the optimization of a new electrochemical cell and its application in measurements of the impact frequency of silver nanoparticles as a function of temperature.
関連文献
Radiation chemistry of solid acetone in the interstellar medium – a new dimension to an old problem
DOI: 10.1039/C7CP06431D
An experimental and theoretical study of adenine adsorption on Au(111)
Robert G. Acres, Xun Cheng, Sofiia Bercha, Tomáš Skála, Vladimír Matolín, Ye Xu, Kevin C. Prince, Nataliya Tsud
DOI: 10.1039/C7CP08102B
Modulation of electronic and magnetic properties of edge hydrogenated armchair phosphorene nanoribbons by transition metal adsorption
Yong-Chao Rao, Peng Zhang, Shun-Fang Li, Xiang-Mei Duan, Su-Huai Wei
DOI: 10.1039/C8CP00880A
Computational analysis of carbohydrate recognition based on hybrid QM/MM modeling: a case study of norovirus capsid protein in complex with Lewis antigen
DOI: 10.1039/C7CP07701G
Metal alloy solid-state nanopores for single nanoparticle detection
Diego Coglitore, Andrea Merenda, Nicoletta Giamblanco, Ludovic F. Dumée, Jean-Marc Janot, Sébastien Balme
DOI: 10.1039/C8CP01787E
Multi-color electrochromism containing green color based on electrochemically polymerized star-shaped phenyl bithiophene
Yujie Dong, Feifei Luo, Lan Chen, Feiya Yuan, Yuejiao Hou, Weijun Li, Shuanma Yan, Yuyu Dai, Mi Ouyang, Cheng Zhang
DOI: 10.1039/C8CP00338F
Theoretical insight into the vibrational spectra of metal–water interfaces from density functional theory based molecular dynamics
Jiabo Le, Qiyuan Fan, Angel Cuesta
DOI: 10.1039/C8CP00615F
The origin of absorptive features in the two-dimensional electronic spectra of rhodopsin
Marwa H. Farag, Thomas L. C. Jansen, Jasper Knoester
DOI: 10.1039/C8CP00638E
Outstanding Reviewers for Physical Chemistry Chemical Physics in 2017
DOI: 10.1039/C8CP91743D
Precursor non-stoichiometry to enable improved CH3NH3PbBr3 nanocrystal LED performance
Sjoerd A. Veldhuis, Xin Yu Chin, Natalia Yantara, Xiaodong Chen
DOI: 10.1039/C7CP07827G
こちらもおすすめ
2-ヒドロキシ-5-ニトロベンジンブロモイドの代替品はありますか?
2-ヒドロキシ-5-ニトロベンジンブロモイドは特定の化学反応に適しているため、代替品は限られています。しかし、同様の構造を持つ2-ヒドロキシ-4-ニトロベンジン...
N-(2-ブロモフェニル)-1-チロール-3-オキソ-3-(ピペリジニル)プロペン-2-イル)ベンゼンアミドを取り扱う際の実験室安全事項は何ですか?
N-(2-ブロモフェニル)-1-チロール-3-オキソ-3-(ピペリジニル)プロペン-2-イル)ベンゼンアミドは有毒で、皮膚や粘膜に刺激を与える可能性があります。...
1,3プロパンジオール,2-[2-(2アミノ-6クロロ-9Hピリミジン-9-イル)エチル-1,1,2,2-D4]-2,3-ジアセタートの市場動向や研究トレンドはどうですか?
この化合物は、新規治療薬の開発に注目されています。市場では、その有効性と安全性が評価され、研究分野では、分子生物学と医薬化学の新たな発見が期待されています。
Succinimidyl-alanyl-phenylalanyl-prolyl-phenylalanine 4-nitroanilide はどの業界で使用されていますか?
Succinimidyl-alanyl-phenylalanyl-prolyl-phenylalanine 4-nitroanilide は主に医薬品開発やポ...
メチル6-アミノ-5-クロロピリジン-2-カーボイル酸について、適用される法規ガイドラインは何ですか?
メチル6-アミノ-5-クロロピリジン-2-カーボイル酸(CAS番号: 1256794-05-4)の使用には、GHS( Globally Harmonized S...
エチル4-(シクロ Pentagonyl)アミノ-2-メチル硫化基ピリミジン-5-カルボキシレートを取り扱う際の実験室安全事項は何ですか?
取り扱いには、耐薬品性の容器を使用し、通気性の良い場所で操作することを推奨します。漏れ時は、SDS(安全データシート)を参照して適切な措置を取ること。手洗いと洗...
(S)-3-ベンZYルピペリジン塩酸塩とは何ですか?
(S)-3-ベンZYルピペリジン塩酸塩は、CAS番号1258940-00-9で表される化合物です。これは、(S)-3-苯基哌啶的盐酸盐であり、主に医薬品の原料と...
3,5-二甲基金剛胺の主な用途は何ですか?
3,5-二甲基金剛胺は、主に医薬品の原料として使用され、また抗うつ薬や抗アルツハイマー薬の開発に利用されます。さらに、化粧品や食品添加物の製造でも重要な役割を果...
ビス(4-メチル-2-ペンチル)フェニルカルボン酸エステルの代替品はありますか?
ビス(4-メチル-2-ペンチル)フェニルカルボン酸エステル (CAS番号: 1398066-13-1) の代替品には、ビス(2-エチルヘキシル)フェノールカルボ...
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










![4-Chloro-3-(trifluoromethyl)-1H-pyrrolo[2,3-b]pyridine structure 4-Chloro-3-(trifluoromethyl)-1H-pyrrolo[2,3-b]pyridine structure](https://static.chemtradehub.com/structs/869/869335-75-1-a9d0.webp)

![2,6-Bis({(2R)-2-[hydroxy(diphenyl)methyl]-1-pyrrolidinyl}methyl)-4-methylphenol structure 2,6-Bis({(2R)-2-[hydroxy(diphenyl)methyl]-1-pyrrolidinyl}methyl)-4-methylphenol structure](https://static.chemtradehub.com/structs/877/877395-58-9-70bf.webp)

