Argentate(i) and (iii) complexes as intermediates in silver-mediated cross-coupling reactions
文献情報
Sebastian Weske, Richard A. Hardin, Thomas Auth, Konrad Koszinowski, Craig A. Ogle
Despite the potential of silver to mediate synthetically valuable cross-coupling reactions, the operating mechanisms have remained unknown. Here, we use a combination of rapid-injection NMR spectroscopy, electrospray-ionization mass spectrometry, and quantum chemical calculations to demonstrate that these transformations involve argentate(I) and (III) complexes as key intermediates.
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Chemical Communications

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