Photooxidation of oxazolidine molecular switches: uncovering an intramolecular ionization facilitated cyclization process
文献情報
Lan Sheng
Photooxidation of oxazoline (OXA) molecular switches through media-induced intramolecular ionization is reported. The formation of the photooxidation product occurs by attack of the flexible donor group (–CH2CH2OH) to the adjacent CC with 1O2 as the oxidant. The novel seven-membered ring sub-structure of the photooxidation product was inferred by HRMS, IR and 1H NMR spectroscopy. Additionally, acid released from solvent photolysis was found to affect the product formation and efficiency of the photooxidation.
関連文献
Photoelectrochemical H2 evolution using TiO2-coated CaFe2O4 without an external applied bias under visible light irradiation at 470 nm based on device modeling
Takamitsu Futagami, Takaaki Sakai, Motonori Watanabe
DOI: 10.1039/C7SE00084G
Anchoring Au nanoparticles on Bi ultrathin nanosheets for use as an efficient heterogeneous catalyst for ambient-condition electrochemical ammonia synthesis
You Xu, Tianlun Ren, Shanshan Yu, Kaili Ren, Mingzhen Wang, Ziqiang Wang, Xiaonian Li, Liang Wang, Hongjing Wang
DOI: 10.1039/D0SE00764A
Lead-free pseudo-three-dimensional organic–inorganic iodobismuthates for photovoltaic applications
Tianyue Li, Yue Hu, Carole A. Morrison, Wenjun Wu, Hongwei Han, Neil Robertson
DOI: 10.1039/C6SE00061D
Bare magnetic nanoparticles as fluorescence quenchers for detection of thrombin
Liangrong Yang, Xiangfeng Liang
DOI: 10.1039/C5AN00519A
Growth of three-dimensional flower-like SnS2 on g-C3N4 sheets as an efficient visible-light photocatalyst, photoelectrode, and electrochemical supercapacitance material
Sajid Ali Ansari, Moo Hwan Cho
DOI: 10.1039/C6SE00049E
Characterization of ginseng saponins using electrospray mass spectrometry and collision-induced dissociation experiments of metal-attachment ions
Suzanne Z. Ackloo, Richard W. Smith, Johan K. Terlouw, Brian E. McCarry
DOI: 10.1039/A908419C
Analysis of interaction between the apicomplexan protozoan Toxoplasma gondii and host cells using label-free Raman spectroscopy
Abida Naemat, Hany M. Elsheikha, Alaa Al-sandaqchi, Kenny Kong, Adrian Ghita, Ioan Notingher
DOI: 10.1039/C4AN01810A
Impact of the ammonia decomposition reaction over an anode on direct ammonia-fueled protonic ceramic fuel cells
Kazunari Miyazaki, Hiroki Muroyama, Toshiaki Matsui, Koichi Eguchi
DOI: 10.1039/D0SE00841A
Improving the activity of CoxP nanoparticles for the electrochemical hydrogen evolution by hydrogenation
James Murowchick, Xiaobo Chen
DOI: 10.1039/C6SE00058D
Catalytic hydrodeoxygenation of biomass-derived oxygenates to bio-fuels over Co-based bimetallic catalysts
Zhen-Hong He, Chong-Shan Jiang, Zhong-Yu Wang, Kuan Wang, Yong-Chang Sun, Man-Qing Yao, Zhu-Hui Li
DOI: 10.1039/D0SE00332H
こちらもおすすめ
4'-ブロモビフェニル-3-メトークシーディ.ActionBarはどのように保存すればよいですか?
4'-ブロモビフェニル-3-メトークシーディ.ActionBarは、冷暗所で、直射日光を避け、密栓の容器に保存し、遠隔場所に保管してください。温度は常温(0〜2...
2-異丙基フェニルヒドラジン塩酸塩とは何ですか?
2-異丙基フェニルヒドラジン塩酸塩は、CAS番号58928-82-8を有する化合物で、構造式はC11H14N2HClです。これは塩基性化合物であり、水に溶けやす...
5-(4-クロロフェニル)-4H-1,2,4-三氮唑-3-アミンを取り扱う際の実験室安全事項は何ですか?
5-(4-クロロフェニル)-4H-1,2,4-三氮唑-3-アミンは取り扱いに注意が必要です。PPEとして防塵マスク、ゴーグル、手袋を使用し、ドラフトチャンバーを...
去甲基雷贝拉唑硫醚はどのように合成されますか?
去甲基雷贝拉唑硫醚は、ベンジミダゾール硫化物と3-メチル-4-ピリジノールの反応によって合成されます。具体的には、2-チオキシドベンジミダゾールと3-メチル-4...
2-ブロモ-5-フロロ-N-(2-フェノールメチル)ベンゼンウレアは安全ですか?
2-ブロモ-5-フロロ-N-(2-フェノールメチル)ベンゼンウレアは、毒性や刺激性の実験データに基づき、適切な取扱いと防護措置を講じることで安全に使用できます。...
対甲苯磺酸酯-四聚乙二醇-四氢吡喃醚の物理化学的性質は何ですか?
対甲苯磺酸酯-四聚乙二醇-四氢吡喃醚のCAS番号は86259-89-4です。この化合物は無色の液体で、分子量は約724.8です。高濃度では溶血性が報告されており...
2-(3-(二氟甲基)-4-氟苯基)-4,4,5,5-四甲基-1,3,2-二噁硼戊環はどのように保存すればよいですか?
2-(3-(二氟甲基)-4-氟苯基)-4,4,5,5-四甲基-1,3,2-二噁硼戊環は、室温で暗い場所に保管し、直射日光から遠ざけ、容器は密閉状態で保存してくだ...
6-アミノ-5-クロロ-2-シクロプロピルピリミジンカルボン酸の代替品はありますか?
この化合物の代替品には、ピロリミジン酸やその類似物、またピロリミジンカルボン酸の他の異性体があります。これらの代替品は、特定の化学反応や目的に応じて選択すること...
5-クロロベンゾ[1,3]二オキセイン-4-アミンに適用される法規ガイドラインは何ですか?
5-クロロベンゾ[1,3]二オキセイン-4-アミンはCAS番号379228-45-2に該当します。この化合物はGHS分類でH314(接触により急性毒性がある)と...
掲載誌
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry










![N-[2,6-Di(9-anthryl)-4-oxido-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoromethanesulfonamide structure N-[2,6-Di(9-anthryl)-4-oxido-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoromethanesulfonamide structure](https://static.chemtradehub.com/structs/122/1227374-64-2-cdb5.webp)



