Spatially encoded diffusion-ordered NMR spectroscopy of reaction mixtures in organic solvents

文献情報

出版日 2018-06-21

DOI 10.1039/C8AN00434J

インパクトファクター 4.616

著者

Ghanem Hamdoun, Ludmilla Guduff, Carine van Heijenoort, Christophe Bour, Vincent Gandon, Jean-Nicolas Dumez

原文を見る

要旨

Diffusion-ordered NMR spectroscopy (DOSY) is a powerful method for the analysis of mixtures. Classic DOSY methods require several minutes of acquisition, and we show here that DOSY experiments can be recorded in less than one second for the challenging case of solution mixtures in low-viscosity solvents. The proposed method relies on a spatial encoding of the diffusion dimension, for which convection-compensation and spectral-selection strategies are introduced. The method is illustrated with the analysis of a reaction mixture, and more accurate estimates of the diffusion coefficients are obtained.

掲載誌

Analyst

CiteScore: 7.8

自己引用率: 5.6%

年間論文数: 653

Analyst publishes analytical and bioanalytical research that reports premier fundamental discoveries and inventions, and the applications of those discoveries, unconfined by traditional discipline barriers.

Spatially encoded diffusion-ordered NMR spectroscopy of reaction mixtures in organic solvents

文献情報

おすすめジャーナル

関連文献

Chiral β3-isocyanopropionates for multicomponent synthesis of peptides and depsipeptides containing a β-amino acid fragment

Syntheses of 12H-benzo[a]xanthen-12-ones and benzo[a]acridin-12(7H)-ones through Au(i)-catalyzed Michael addition/6-endo-trig cyclization/aromatization cascade annulation

Rh-Catalyzed aminative dearomatization of 2-naphthols

Covalent capture of OGT's active site using engineered human-E. coli chimera and intrastrand DNA cross-links

Cobalt(ii)-catalyzed regioselective C–H halogenation of anilides

A red-emitting fluorescent probe for the detection of Hg2+ in aqueous medium, living cells and organisms with a large Stokes shift

trans-Hydroboration vs. 1,2-reduction: divergent reactivity of ynones and ynoates in Lewis-base-catalyzed reactions with pinacolborane

Umpolung cyclization reaction of N-cinnamoylthioureas in the presence of DBU

Back cover

Reduction of aromatic nitriles into aldehydes using calcium hypophosphite and a nickel precursor

こちらもおすすめ

3-イチチルビフェニルはどのように合成されますか？

8-溴-5-三氟甲基喹啉はどのように合成されますか？

ジメチル4-(4,4,5,5-テトラメチル-1,3,2-ドioxaborolan-2-基)-2,6-ピリジンジカルボイル酸フェニルアミニドの代替品はありますか？

N-(3,5-ヘキサクロロ-4-ピリドインイル)-8-メチオキシ-5-キノリンカーボン酸の市場動向や研究トレンドはどのようなものでしょうか？

イソステアロイルグリセリルは安全ですか？

1-(二苯甲基)-3,3-二氟-氮杂环丁烷の市場動向や研究トレンドはどうですか？

3-チオフェンスチオールの物理化学的性質は何ですか？

2-Methyl-2-propanyl (2S)-2-(aminomethyl)-1-piperidinecarboxylateは安全ですか？

CAS番号1316822-90-8の化合物は安全ですか？

Tert-butyl 2-(2-羟基乙基)哌嗪-1-羧酸はどのように保存すればよいですか？

掲載誌

Analyst

おすすめ化合物

1-Isobutyl-7-methoxy-2,3,4,9-tetrahydro-1H-beta-carboline

1-[6-(1H-Imidazol-1-yl)-3-pyridinyl]methanamine

8-Bromo-7-fluoro-2-methoxyquinoline

4-azidosalicylic acid N-hydroxysuccinimide ester

Isomorellinol

おすすめサプライヤー